Even without changing voltage, raising frequency when already at or near the frequency ability of a node, is much more than linear.
Linear heat production occurs only at low powers. In the middle it isn't quite a square of the frequency, but it's still a power of 1.3 to 1.5.
Once you get toward the top of the ability of the process, its pretty much a power of 2.
My point being, frequency scaling as a method of increasing ST performance is a terrible strategy if that is what your architectural strategy is betting on.