A standard deadbolt/door is already stronger than a window, so to enhance security you need to do something about the windows. Really I don't know why plexyglass is not standard for home windows, I guess it's more expensive to make? Double pane plexy would be pretty strong I would think and it would perhaps even help during a a mild storm where debris goes flying. Maybe not hurricane but something a bit less powerful that would normally smash glass.
Of course there are simple things you can do like drive longer screws that hold the strike plate and such, it's so trivial to do may as well do it even though it's not your weakest link.
A security system with motion sensors is best bet to react at an invasion (wont stop it though) Cameras are also good to have. Basically these are your 2nd or 3rd line of defense and may even be a deterrent. I have a sign on my front lawn from the security company and I also have stickers on my windows. I never bothered with the window sensors, because I have motion sensors anyway. For window sensors to even work you need glass break AND latching, because both can be defeated easily. A latching one will be defeated by breaking the glass and a glass break sensor will be defeated by forcing the window open or using a glass cutting tool that wont cause a smash sound or vibrations.
I have door contacts and motion sensors and that covers everything. Idea is to have a choke zone sensor. If somebody breaks in through the kitchen window for example they're not going to steal a couple pots and pans and leave through the window. They're probably going to go to the living room and see what else they can steal, and walk around, then use the door to leave. This will trigger the motion sensor and door sensor.
I suppose a really smart thief would build a robot and throw it through a window then control it from a remote location but I have yet to hear of anyone doing that, yet. TBH I'm kind of surprised. Would be fairly easy to do for someone into robotics and easy to not get caught and you just put a couple pounds of C4 on the robot and detonate it if the owner tries to stop the robot. Nobody will ever know who made the robot or where it came from. Thankfully robot crime is not really something that is happening, yet.
