Well, the benefits would be huge to side step the competitors and introduce e.g. 5 nm or below several years before anyone else.
If going directly for some disruptive technology like graphene that doesn't directly depend on all previous semiconductor process technology advancements it ought to be possible.
Sure, the risks would be high, but so would the reward in case of success. Basically you could completely dominate the semiconductor industry. That's a win worth tens of billions of dollars.
Well, I guess Intel nicely showed that you don't need to skip any nodes to get a huge, long leadership position on bleeding edge nodes, just by following the roadmap (which doesn't give you massive risks), but at a pace that no one can follow. Like I already said, following the roadmap of Moore's law is already difficult enough. A lot of people already gave a lot of good answers to your question, I'm not sure what you don't understand about the explanations.
But you also mention other technologies like graphene. Those things also get on the roadmap. The semiconductor industry really isn't a cheap business, it's best to follow the most economical path, which happens to be pretty publicly available (I already explained that 1 company can't just develop a node that lies 6 or 8 years into the future). If a technology is available for 1 company, other companies can very likely also implement it, so it's really an issue of money, how fast you can implement technologies and execute the roadmap.
Example: As we near the end of Moore's law, more drastic changes are required to keep up with it and sort of continue Dennard scaling, and in the relatively near future, one of those technologies that will have to be implemented, happens to give a huge improvement in power consumption, namely III-V materials, as replacement for silicon. So while the other companies are still figuring out how SiGe or Ge works, or trying to build 450mm fabs, Intel with its ~4 year lead will have such a technology as you mention (if it indeed gives something like a 10x lower power consumption and 1,5x higher clock speed).
Maybe TSMC/Samsung/... will again do some magical marketing trick to try to implement this technology faster, but that will probably be at the cost of other things such as transistor size.