Originally posted by: GarlicBreath
I have some experience with skunks. Here are your options:
1) Headshot: .22 is sufficient. If you hit the brain, the skunk won't spray. You can bait the skunk out at night with bacon.
2) Trap and drown: This is probably the best option. Rent or borrow a box trap like this one:
http://www.safeguardproducts.com/
Some city animal control departments will loan you one.
Bait it with bacon. Set it a night. Once the skunk is inside, wait til daylight, then walk up slowly and throw a blanket over the whole trap. The skunk won't spray. Then carry the whole thing to somewhere with water deep enough to cover the whole thing. This is the tricky part; you can't stand the trap on end (it'll open) so a trashcan is out. If you have a lake or pond close, you're all set. Otherwise, the bathtub might work. Check to make sure the trap fits before capturing the skunk!
3) Mothballs or bleach: You may be able to convince the skunk to voluntarily move if you put mothballs or bleach in his burrow.
Good luck.