LLC/VDroop should be set so that the voltage you set for VCC in the BIOS matches what the voltage actually is (as reported by CPU-Z or similar), it doesn't have to be *exact* just as close to it as possible.
What that setting will be?... no idea, ideally it should be the maximum setting, 100%, Level 1, "Enabled" (depends on the motherboard).
However this sometimes overvolts, ie: you set 1.2v in the BIOS and it ends up being 1.22v when under load.
For mine, LLC 1 (100%), is within 0.004v of what I set it to in the BIOS. Some people with the same motherboard, and same CPU, get overvolted at LLC1, and have to use LLC2 (75%), or LLC3 (50%).
LLC only really comes into play when using Offset voltage, when using Fixed voltage, it should be enabled, or 100%.
It takes a bit of playing, a bit of writing down numbers, to figure out which LLC setting is the best one to use for your configuration. (unless your only options are Enabled/Disabled).
PLL should be left at stock... 1.8 to 1.85
PCH and VTT should be somewhere between 1.03 and 1.08v
All of those should be left at stock until you get to about a 125% overclock. Or you are trying to overclock your RAM at over 125% of it's speed.
You shouldn't have to touch any of them till you are around 4.5GHz... or 2200 on your RAM... I say *shouldn't*, but you may have to.
VCCSA should be 0.925v ... and just never touched really, unless you can get to 5.2GHz or something, *then* you might have to.
If RAM is cause problems, then yeah... just get rid of it... underclock it to 1333, 1600, whatever is stable... ignore it... overclock your CPU and just set things to whatever it takes to get that stable.
Once you've figured that out... then consider overclocking RAM... when doing that, set the CPU back to default values... ie: ignore it... then focus just on RAM see what it takes to get that stable.
I wouldn't really bother OC-ing RAM, there's very little difference between 1600 and 2000 for me... maybe if I was using the iGPU it would have more of an effect, but it's only about a 4% increase in speed, for a 125% overclock, and that's just throughput, normal RAM usage/speed is practically unaffected by the overclock.
The only reason I do, is because my RAM will take it while still being undervolted, if you have to add voltage to your RAM (DRAM, whatever it's called in our BIOS) just give up, it's not worth it.
NO ONE will be able to say something like: "set this to this exact voltage, and set this to that exact voltage" it just won't happen, you have to figure out what your ranges are for your configuration... they might be really good, they might be really bad.
Delayed Edit: Anyways, once you figure out your top-end for CPU, and RAM... then work on merging them, because by then you'll have a good idea of the behavior of your system... what sort of errors occur when CPU isn't stable, and which occur when RAM isn't stable, what it took to correct it.
Also keep in mind, the BIOS version you are using, if you really want to get picky, often one BIOS will be better than the next... some people use nowhere near the latest one for this reason... the latest one is v3.0... and they might be using 1.3 because it works best for their system.
Personally, I just downloaded all the versions for my motherboard, and tossed them on a USB key so I can randomly or methodically pick which one to use. I don't really suggest this, because it's just a pain in the ass and more crap to wrap your head around. But it might be worth trying the latest one, or an earlier one... if you're lucky your motherboard manufacturer will actually say what changes were made, some don't.