These are what most of the risers come with. I think sata is on 12v rail vs 3.3 or 5v for molex and that is the reason. Could be wrong though
Yeah, those came with my risers too and I started out by using a few of them, but NEVER had more than one GPU per single SATA power cable with ONE SATA>Molex power plug. I have a couple of RX470 Nitro's going now and the black SATA power plug is hot to the touch - can't leave my fingers on it for more than 5- seconds. My IR temperature gun (fun toy, btw!) shows the plug as ~40-45C...
It seems the most desirable would be PCI-e plug powered risers we saw discussed a month or so ago, but I can't seem to find them anywhere.