Originally posted by: magreen
Hey ed21x, can you link me to some info on how radioactive decay rates can fluctuate with pressure, temp, ambient concentrarion, etc.?
Thanks. Sounds interesting.
I typed in "effects of Temperature, pressure, diffusion" and got this as my first search result (from ScienceDirect)
This experimental study shows that large-radius cations like those of uranium can be incorporated as large amounts into mantle silicates via a diffusion process: as expected, this process is activated by high temperatures and/or long run durations, but it appears that there is no negative effect of high pressure. Indeed, pressure is known to lower the diffusion coefficients (Poirier, 2000): but after the results we obtained in this study, we can assume that the effect of temperature was substantially more important than the effect of pressure, and high temperatures combined with long run durations could efficiently activate the diffusion process of the U incorporation at high P. We obtained diffusion coefficients for U into the Al-CaSiO3 perovskite at high P and T, in the same order of magnitude than those of U into diopside observed at high T: our experiments could not be considered as so-called diffusion experiments (like those described in the review by Béjina et al., 2003 F. Béjina, O. Jaoul and R.C. Liebermann, Diffusion in minerals at high pressure: a review, Phys. Earth Planet. Int. 139 (2003), pp. 3?20. Article | PDF (214 K) | View Record in Scopus | Cited By in Scopus (12)Béjina et al., 2003), but they allowed us to quantify the effect of both run duration and temperature on the diffusion process of uranium into the Al-CaSiO3 perovskite. Two other characteristics are also essential for such diffusion: the size and the charge of the cation diffusing into the Ca-perovskite matrix. In fact, U4+ is slightly smaller than Ca2+, and furthermore its charge is twice bigger: these two arguments are in favour of the relatively easy diffusion of uranium at high P and T, that we could observe in this study.
from Experimental high pressure and high temperature study of the incorporation of uranium in Al-rich CaSiO3 perovskite
Steeve Gréauxa, , , Laurent Gautrona, Denis Andraultb, c, Nathalie Bolfan-Casanovac, Nicolas Guignotd, 1 and M. Ali Bouhifde (from Science Direct)
Of course this is just talking about diffusion affects of Uranium into some Silicon matrix by temperature and pressure. CaSiO3 is of course the mineral that replaces soft tissue in decaying organisms, so increasing diffusion of Uranium into this matrix at high temp/pressure will essentially make the specimen more radioactive. It's a stretch, but I'm not really trying that hard.
One thing to remember is that when searching for proofs, never type "Scientific Proofs that Radioactive dating is true/false" because that is just begging for biased whackos from the entire spectrum with an agenda. Research indirectly on factors that might affect carbon dating. For example:
another article:
Effect of pressure on the decay rate of 7Be
Institute of Earth Sciences, Academia Sinica, Nankang, Taipei, Taiwan, ROC
Received 10 February 2000; Revised 25 April 2000; accepted 11 May 2000. Available online 12 July 2000.
Beryllium-7 in Be(OH)2 gel was compressed in diamond-anvil pressure cells up to 442 kbar at room temperature. By counting the activity of 7Be, the decay rate for the conversion of 7Be to 7Li via electron capture was measured. The decay constant of 7Be, ?, was found to increase, but the rate of increase decreased with increasing pressure. A quadratic regression of the data yields (?-?0)/?0=(4.87×10-5)P-(5.9×10-8)P2, where the subscript zero denotes zero pressure and P stands for pressure in kilobar. Thus, ? of 7Be increases by about 1% at 400 kbar. The observed data set can be rationalized by an increase in electron density near the nucleus of 7Be at high pressures. This result may bear some implications for the conversion of 40K to 40Ar, which has been widely adopted to date geological events.
This article shows that pressure/temperature can have an effect on radioactive decay rate of Beryllium. Of course this isn't directly asking "is radioactive dating accurate?" so that you avoid biased answers, but you can get tested information and make your own assumptions.