I see a few misconceptions here people.
First off, Ethylene Glycol is a poor heat conductor, when mixed 50/50 with water it will inhibit corrosion, increase the boil over temperature (water boils at 212F, a 50/50 mix will boil over at 240F - 270F depending on altitude and barometric pressure).
Straight water is much more efficiant at conducting heat but will rapidly corrode your cooling system (especially on iron block/aluminum headed engines or on any engine where disimilair metals are present).
Distilled water should be used because standard tap water has minerals in it which will fall out of suspension onced pressurized and heated (not to mention the flouride, chlorine, bromide and other chemicals which are found in tap water).
Remember too that boil over protection is also accomplished by pressurizing the cooling system, usually to around 15 to 17 pounds per square inch.