Actually I'm fairly certain the first Pentium was 66MHz, then there was 60MHz released later for those that didn't work so well at 66.
75MHz is actually SLOWER than 60 because of the 50MHz memory/L2 cache and 25MHz PCI/VESA bus.
Pentium is the first x86 with 64-bit bus BTW.
60 and 66 = Socket 5 (supports 1x multiplier only, 5V, also known as the Pentium Oven even though it uses less power than any of today's CPUs).
75, 90, 100, 120, 133, etc. = Socket 7, started at 3.3V I think, jumper selectable multiplier from 1.5x to 3x originally, range later changed with Pentium MMX/K6 to 2x to 3.5x and 2x to 5.5x with K6-2/3.