I think a quickie electronics lesson is in order.
The OP mentioned using a 2-molex connector to provide power to a 6-pin adapter for a PCIe graphics card. (This actually applies to pretty much any use of splitters/adapters and power supplies in general.)
DO NOTE THAT USING TWO MOLEX CONNECTORS FROM THE SAME WIRE (IE A BRANCH CONNECTOR FURTHER DOWN THE SAME WIRE) IS NOT WHAT A TWO-MOLEX CONNECTOR ADAPTER WAS INTENDED FOR.
Because of the design/layout of those wires, ALL of the current must flow through the first part of the wire. So, if you are trying to draw a theoretical maximum of 72W from each molex connector, you are still drawing a nice 144W from the entire line. Imagine an A/C duct. Would you use the same 12" ducting that goes out to each individual room to feed from the A/C itself? No, you'd most likely use a 24" duct or (and this doesn't really happen but you get the idea) 2 12" ducts. Let's look at it in a graphical way... let = represent a wire carrying a large amount of current (too much current), and - represent a wire carrying up to its rated current. let | represent a molex connector.
If you attempt to use two molex connectors from the same line to power your adapter, you will create this situation:
===========|---------------|
This is because both connectors are sharing a common conductor (even though they are technically in parallel). I cannot think how to explain it much better, but just remember that all of your power has to come from somewhere, and if you try to split something too many times you will regret it later.
So don't go cheap out and buy an L&C 400W PSU because it's $50 less, and then using a molex splitter to use the same line that goes to your HDD with your PCIe adapter. I can pretty much guarntee you will set fire to your PSU if it lasts long enough (and since we're talking about cheap PSUs there probably isn't any kind of OC/OL protection), but in either case you will be sacraficing that PSU and then still have to pay the price of the more expensive PSU, as well as any other components the PSU destroys on its way down.
My national electric code teacher always says, "Forget about guns - we should have a 10-day waiting period on screwdrivers; anyone can go out and buy one and think they know what they are doing."
Just remember, splitters and adapters are designed to make things do something the manufacturer did not intend for you to do (if they intended for you to do it they would've made it so you could do it without any extra splitters or adapters!), as such use of those devices should be reserved for the most extreme and/or limited of circumstances, and only when you've done your homework to know that it's 110% safe and approved. I mean, honestly, I can mount a chevy 454 to a lawnmower given enough adapters, but is that really a good idea?
To reitterate, all the power must come from somewhere.
I would much rather take the time to answer peoples electronics questions about matters like this before they are put into practice, than listen to people whine and cry when XYZ psu fried their $2200 playtoy mommy and daddy bought them.
That's about all I've got to complain about this time around =).