I took a look at what you did & what you did wrong. Close, but no cigar. There's nothing at all wrong with using the Law of Cosines either. It's perfectly acceptable for the resultant of two vectors. (I'm pretty qualified to teach physics too.

)
Anyway, your "formula" that you're using is wrong. The y component works out okay, but that's because the sin of an obtuse angle is the same as the sin of it's supplement. But when you calculate the x-component, you should have a minus sign, not a plus sign. Else, you should note that you're finding the supplement of the actual angle.
And, even with that, your 91.5 has a rounding error. Never round off before the last step. Rather than 1.5 above 90, it should be 1.6 below 90: 88.4 degrees. 88.411140664674396634503818597918 according to my calculator. (Of course, rounded off to the correct number of significant digits, which would be 88 degrees.)
The other answers work out to 38.572650822227776481970894599430
and
50.309788436157518979259113035067
Are you doing this tutoring because it's a friend or something? Are you getting paid for this?? (Scary, since you should know that the law of cosines is perfectly acceptable in physics.) Of course, it takes a little away from an intuitive approach, which is why most people would the method you're using (although, perhaps a slightly different style.) Plus, the way you're approaching the problem is pretty efficient when you're trying to find the resultant of half a dozen vectors. I particularly liked the table you started making, too.
I'll upload a diagram in a couple minutes. BTW, you'd have probably noticed this if you hadn't drawn your angle so close to 90 degrees.