Exactly like Paul said. Socket A Sempron CPU front side bus is 166 MHz DDR, 64-bit wide. Giving the chipset dual channel (128-bit wide) 166 MHz DDR RAM is not going to improve performance at all, simply because the CPU bus forms the bottleneck, not the RAM bus on the other end.
Socket-754 Semprons in turn attach the RAM directly to the CPU, no CPU front side bus there at all. Thus, from the same RAM, you get much better performance than on socket-A. Access latencies are drastically lower, throughput is quite impressively higher as well.