My dad did it, and I do too. He told me if you keep track of the mpg, you get a feel for when your engine isn't running right, by noticing a drop in mileage (as was pointed out earlier in the thread, by lxskllr). Really no other reason to do it, except maybe to satisfy your OCD.
Eli, next time you have that sort of over-pump, you need to request that the gas station attendant shut down the pump and call someone who can check the "proof" of the pump with a 5 gallon prover can. They'll be licensed by your state's weights and measures folks to check the pump, and verify it's pumping the correct amount (and correct the adjustment, if necessary). Tell the station attendant that you will be calling your state's weights and measures department, and complaining about the problem (the number should be on the sticker that the prover company put on the dispenser).
If they've been notified of a problem, and continue to dispense fuel from that pump, and it's later proven that it was out of calibration, they can face some pretty hefty fines. Also, once the calibration folks run a "proof" on the dispenser, they'd be able to tell how far off it was from reality, and you can calculate how much was actually pumped (and how much the gas station owes you in return, for overcharging you).