Just to be clear, Edrive requires an Edrive capable version of Bitlocker (and thus Win8.1 Pro or higher). Edrive itself offers no data encryption. There are other requirements, like a suitable EFI BIOS, a supported SSD, and a TPM (or you can change Bitlocker to use alternate authorization methods such as a passphrase if you don't have a TPM).
The main assumptions I'm making regarding Evo and EDrive are that 1) it will only work on a fresh Win 8.1 install and 2) the Evo security status for EDrive must be set to "Ready to Enable" prior to 8.1 installation.
I'm also assuming that Win 8.1 cannot be simply reinstalled on an existing EDrive Evo.
Here's what I would do:
1) Backup your data off of your existing install.
2) Download a copy of the
PSID revert utility linked in this thread while you still have a working OS. Although not needed, you may wish to prepare a bootable USB/CD with Samsung's Secure Erase utility via Magician.
3) If you haven't already, update the Evo firmware using the
Performance Restoration tool. Though we are not interested in running Steps 1-3 of the Performance Restoration Tool, you may need to let them run anyway. In the future if Samsung offers the new firmware standalone or through Magician I'd use that instead.
4) Use the PSID revert utility linked in this thread on your Evo to reset it's EDrive settings. This will destroy all data on your Evo. You will need the 32 character PSID printed on your Evo. This should also have the effect of performing a Secure Erase, but you could always run a separate one after the revert if you wish via standard methods.
5) Use Magician to change the EDrive security status of your Evo to "Ready to Enable" via any of the following methods. If you have an existing computer with Magician, you may just want to temporarily connect your Evo to it. If you have a single computer but have an extra HDD/SDD, you can install just Windows and Magician on that drive to change the EDrive status of your Evo. Finally, you always just install Windows and Magician on your Evo (temporarily) to change EDrive status. In the latter two cases, you don't need or want to activate Windows, patch it, or install any drivers or apps.
6) Install Win 8.1 Pro (or higher). Then install Magician and verify EDrive status is "Enabled."
7) Enable Bitlocker. You might need to disable TPM/enable passphrase if you don't have a TPM. You should not be asked to either "encrypt whole disk" or "encrypt data only." If you are, then EDrive + Bitlocker isn't working, only Bitlocker with CPU encryption (though with hardware AES-NI support in certain CPUs the performance can still be quite high). And of course,
if you don't enable Bitlocker, then Edrive is not encrypting your data regardless of what Magician shows for the Evo's status.