Are you asking what the probability is of getting just 1 six in 100 rolls?
100*(5^6)^99*(1/6)
Are you asking what the probability is of getting at least 1 six in 100 rolls is?
It's pretty damn good!
1 - (5^6)^100
As a percent, 99.99999879253265275863333993072% probability of getting at least 1 six.
However, I think I see where your logic if failing you.
This still doesn't mean that if you roll 99 times and not get a 6 that you're more likely to get a 6 on the 100th roll to make up for it. You seem to think that if you roll a non-six 99 times that the probability of getting a 6 on the 100th roll is
99.99999879253265275863333993072% to make up for the non-6 rolls. This is (for the 10th or so time in this thread), called the gamblers FALLACY. As in false. As it "it just ain't true."
If you roll 99 times and don't get a 6, then there's a 1/6 chance that you're going to get a 6 on the next roll, and a 5/6 chance that you're about to succeed in rolling 100 times and not getting a 6. Dice don't have brains. They can't remember what just happened.
Maybe I can help.
First, look at my table of possible rolls for rolling a die twice.
11 12 13 14 15 16
21 22 23 24 25 26
31 32 33 34 35 36
41 42 43 44 45 46
51 52 53 54 55 56
61 62 63 64 65 66
Now, let's say you rolled a 5. According to your argument, a 1,2,3,4,or6 would be more likely on the next roll, because they haven't occurred yet. They're "over-due."
Look at the 5th line: After rolling a 5, there's a 1, a 2, 3, 4, 5, and a 6 possible for the next roll. All with equal probability.
If you were to make a sample space table for every possible outcome with 100 rolls of a die (good luck, it'll be freaking huge, far surpassing the number of grains of sand on a beach, heck, the number of grains of sand on earth, even exceeding the number of grains of sand on all possible planets in all of the universe. i.e. freakin huge number) Anyway, out of the huge freaking number of possibilities, every one of them having the exact same odds of happening, you'll notice that there are a heck of a lot of them where the first 99 rolls don't have a 6. Of these, the 100th roll is a 1 1/6th of the time, a 2 1/6th of the time, a 3 1/6th of the time, ..., and you guessed it (but want to deny it) a 6 1/6th of the time.
For what it's worth, the odds of rolling:
1,2,6,4,5,2,3,1,3,5,2,3,1,1,2,5,3,2 in that exact order are EXACTLY the same as rolling:
6,6,6,6,6,6,6,6,6,6,6,6,6,6,6,6,6,6
Or another way to put it, in a lottery drawing, the odds of 1,2,3,4,5,6 coming up are exactly the same as any other 5 ball combination.
Oh, and for "anyway you must not teach that high a level of math" - actually, yes, I do. This concept is taught in 9th grade in New York. (But I teach up to the level Calculus II as an adjunct professor - I don't have the students available in my school to teach a higher level course, and I hate teaching statistics.)