I would agree, going RAID5 with an add-on controller would be the ideal solution with speed and reliability being of high importance. No more than three drives though: the more drives you add to a RAID5, the slower it gets.
If that is cost prohibitive, the next best solution would be a single SSD and do periodic image-based backups (which you would have to do anyway if you went RAID0). While RAID0 would theoretically double the performance of an SSD, we're not talking about reducing load times from 10 seconds to 5 seconds here. We're talking about cutting a second in half at the most. At this point with most data the performance difference isn't meaningful, but you also double your chances of hardware failure, since the loss of either of the two drives will kill your volume and cause you to undergo a long restore process. Using one drive reduces the chances of that, allows the OS to TRIM the drive, and also eliminates the RAID as a point of failure.
If you're satisfied with your current performance, you'll find a single SSD to be blisteringly fast. They're a whole new paradigm of thinking, and I honestly don't see the point of RAID with them at all except for the following scenarios:
1. Redundancy, as in RAID1 or RAID5, because you can't afford for your system to be down when a drive dies.
2. Databases being accessed by truly massive numbers of processes simultaneously.