I don't think you understood; click the TechNet Sysinternals link that MrChad posted and download Junction v1.06. It's a zip file, so you'll need to extract 'junction.exe'. Since you're running XP Pro it would be easiest to just copy junction.exe to the root of your system drive (C:\junction.exe). When you open a command prompt, navigate to C:\ and 'junction' will be available from the commandline ( C:\>junction ). Here are examples of syntax:
Using Junction
Usage: [-s]
-s (Recurse subdirectories)
Examples:
To determine if a file is a junction, specify the file name:
C:\>junction c:\test
To list junctions beneath a directory, include the s switch:
C:\>junction -s c:\
To create a junction c:\Program-Files for "c:\Program Files":
C:\>md Program-Files
C:\>junction c:\Program-Files "c:\Program Files"
To delete a junction, use the d switch:
C:\>junction -d c:\Program-Files
To answer your question; yes, junction.exe can parse any drive. In the above example of how "To list junctions beneath a directory, include the s switch:" this command is used:
C:\>junction -s C:\
...which will recursively display all junctions under C:\.
To display another drive or volume simply change directories:
C:\>junction -s E:\
.