Disconnect the psu from the mb. Use a short length of wire to connect the green wire to any black wire on the 20/24 pin plug of the psu (the one that connects to the mb). See if the psu starts. If not, disconnect the power leads from the other devices in the rig, and try again. Just starting does not always mean the psu is good, but if it starts by itself with the test, and does nothing when connected, the problem is usually something other than the psu.