Don't know if optimum settings are posted anywhere but I agree with Quaggoth.
Consider this:
If you take a look at the file size of a typical home pc you'll find hundreds of files that are 1k in size. You'll find hundreds more that are less than 4k and thousands that are less than 64k.
The smallest block size you can choose is 4k. So each of those 1k files is actually taking up 1 block of disk space. Windows doesn't store 4-1k files in a 4k block, 3k is waisted. For 64k block sizes, 63k is waisted. So, the block size you choose has an effect on the overall storage capacity of your hard drive.
Choosing a 4k block in a raid configuration allows files of 4k or less to be read off of a single drive, speeding up data access. A file larger than 4k may slow things down because you may have to wait for 1 of the 2 (or more) disk drives to seek and retrieve the data. One of them may be busy with another operation when the read request is issued.
Defining a block size of 8, 16, 32 or 64 speeds up access because smaller files can be retrieved from a single disk. But you sacrifice true disk capacity when you do this.
For optimum capacity (as Quaggoth states) choose 4k.
For optimum speed choose 64k.
For somewhere in between choose 8, 16, or 32.