Ok, just went through this with my HD5850s. If you don't see a "CrossfireX" link within the Catalyst Control Center's "Performance" tab, then the installation isn't registering with the drivers.
- First thing I'd do is test both cards separately in the top slot to make sure they both work correctly.
- Assuming they do, the next thing to do is to uninstall all ATI drivers (and preferably use a driver cleaner just to make sure), shut down, and then install the second card with the crossfire connector attached. (I'd read that you should load up without that, but that didn't do anything good for me)
- When it loads into windows, you'll need to install the ATI drivers, preferably the latest (11.10). Some people say you then need to restart and install a second time (for the second card), but I don't think that actually does anything.
- Once Catalyst Control Center is installed, you should go into the control panel and see if the "CrossfireX" appears right next to the "Overdrive" link in the "Performance" tab.
- If CrossfireX shows up, it will probably default to enabled unless something else is wrong.
- If CrossfireX does not show up after all these steps, then either you have a crossfire connector problem or a motherboard slot problem (at least that's all I can think of). I'd then test each card alone in the bottom slot.
Let me know if this works. No reason to do any game tests if CrossfireX doesn't appear in the control panel...and while the CAP is necessary to get specific game optimizations, it isn't critical to get CrossfireX to appear in the Catalyst Control Center.
By the way, you should post your system specs when you ask for help on advanced setups. We need to know your motherboard and your powersupply, and it would help to know your CPU too. And just as a personal example, I could not get crossfireX to become enabled, despite seeing the option in Catalyst, until I pulled some memory out. Crossfire would not function with a mixed set of ram (2x4GB, 2x2GB). So you ought to post your memory setup too...