Congrats to G41184b with the correct answer: 2/3.
There are four possible combinations with two children (B=boy, G=girl) : BG, GB, GG, BB.
We know there is one girl for sure, so that eliminates BB, leaving BG, GB, GG. Of those three, two have a boy sibling and one has a girl sibling, meaning a 2/3 chance of the other child being a boy.