PrimoCache makes a lot of sense for steam library on HDD. I do that on a few of my computers.
With a 1TB SSD + 6TB HDD, I'd recommend splitting the SSD into two partitions (split somewhere between 500/500 and 800/200). Install Windows to the first SSD partition, and have PrimoCache use the second partition as cache space to accelerate the HDD.
Having the OS directly on the SSD makes it a bit faster, and removes some possible failures that can cause your OS not to boot (pretty rare with PrimoCache, but still possible). It also means you can manually install some apps/games directly to the SSD if desired.
With only the steam library being cached by PrimoCache, you can consider enabling delayed write caching to speed up game updates. That's kind of dangerous on an OS drive (power cuts can corrupt the whole system - I've had this happen personally!) but not a big deal for games that you can re-download or repair.
With a 1TB SSD + 6TB HDD, I'd recommend splitting the SSD into two partitions (split somewhere between 500/500 and 800/200). Install Windows to the first SSD partition, and have PrimoCache use the second partition as cache space to accelerate the HDD.
Having the OS directly on the SSD makes it a bit faster, and removes some possible failures that can cause your OS not to boot (pretty rare with PrimoCache, but still possible). It also means you can manually install some apps/games directly to the SSD if desired.
With only the steam library being cached by PrimoCache, you can consider enabling delayed write caching to speed up game updates. That's kind of dangerous on an OS drive (power cuts can corrupt the whole system - I've had this happen personally!) but not a big deal for games that you can re-download or repair.
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