Unless you are only looking to make a simple page and never get into serious web design, I would STRONGLY consider learning basic HTML coding (as advanced as complex table work and forms) before using ANY program. It's a lot easier to understand what is going on when you do that, and should frontpage screw up (and it will) it will be a lot easier to fix its mistakes.
Just a suggestion.
But if you want to ignore it, yes, frontpage is excellent to start with. If you can use MS word, you can use frontpage.