Jack,
Would agree with Newf that it sounds like too much paste.
The simple principle of thermal paste (AS5 or any other) is that getting direct contact bewteen the CPU and your copper heatsink would require mirror like machining to a level that isn't practical.
Therefore when you place the two together you end up with tiny airgaps between the two surfaces and air does not conduct the heat very well, so we use a thermal conductive paste (AS5 being one of the better ones) to fill these tiny airgaps, as the thermal paste conducts heat better than air.
The problem is that thermal pastes (AS5 included) don't conduct nearly as well as direct contact with your copper heatsink, so in theory you need to apply a VERY thin layer that when the heatsink is mounted, gives a uniform contact surface with no air gaps.
This of course is the theory, as making that thin a layer and not disturbing it when attaching the heatsink is not practical, but too much paste will definitely reduce the effectiveness of your heat transfer.
I have found recently that the best way to apply a thin layer of AS5 is:
a) Warm it up in a warm water bath (about 30-40C) this makes the paste less viscous and easier to spread.
b) Apply to the CPU outside the MB using the foam transit pad to seat it on, and I warm the CPU with hot-air stripper/hairdryer so not cold!
c) Apply 1/2 BB spot of paste and I use a fresh/new razor blade to spread as evenly and thinly as practical (you should be able to read the AMD logo/description through the paste)
d) Carefully refit pre-pasted CPU not touching the top surface, which is much easier now with zero force CPU clamps.
e) Carefully fit CPU Heatsink/cooler trying not to disturb the paste too much.
Some report burn-in times for AS5 of 100+hrs, but personally I see little difference now even after months, so you should see temps back at least at your lower ones straight away.
Ridesy