For whatever use this may be to anyone:
Turbo V: auto
PLL Overvolt: disabled
LLC: 1 (for offset), and auto for fixed (which shows as 1)... on this board 1= 100% (supposedly, lol)
RAM: 1.450v (from 1.5, otherwise stock clock/timings 1600/9/9/9/24)
PLL voltage: 1.603 (from 1.832, does have an effect but not much so I undervolt)
C1E enabled, C3/6/States disabled
IGPU stuff all disabled
Otherwise defaults (for this board)
22C ambient... ignore the "watts" (was going to, didn't bother including) although load voltage does almost equate to Package watts.
CPU & Exhaust (140) fans are set to 25% (62 of 255 on this board, lowest they'll go and still spin up from "off") with target temp 45C, takes about 3 minutes for this board to spin them up to full/100%... intakes (2x140 front, 1x120 bottom) are set to a constant 5V... so temps could be much lower (-6 at idle, -2 at load or something, not really enough to make up for the noise)
My 24/7 config is 4.2GHz with 0.01v less than seen here, VTT & PCH are slightly undervolted, and RAM is overclocked to 1800 otherwise same settings as here.
Regarding TIM, I've done it 3 times now with this CPU/Heatsink, right now I'm using about this much:
(like, a cylinder of that width/length at the scale of the image not actual scale - "rice grain")
First time I used about 3 times that much, second about 2.5 times... can't really say between those 3 amounts it's made much of an effect.