
good luck keeping the 2 separate. people do not generally have anywhere near the required technical sophistication to keep the 2 separate. even among highly trained scientists... years of daily work in laboratories... day-in day-out, I've observed astonishing ineptitiude, incompetence, sloppy techniques, and countless experiments gone wrong dur to faulty assumptions.
and yet a joe schmoe is going to perform this chemistry experiment correctly in his poorly lit disheveled garage with some bent tubing on his weekend and between shifts? not a chance.
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but it won't be a separate portion because a lot of that will be mixed in with the rest of the batch,.. every batch due to poor training, bad internet advice, lack of skill, lack of precision, improper equipment, unintentional sloppiness... etc, etc, etc. the point being the poision will be diluted in the final product, not purified in a separate and distinct aliquot... it'll be in the bottle you serve up to your buddies.
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this point is irrelevant and shows a general lack of understanding that is quite frankly jaw droppingly astonishing. would you say that the relative concentration of poison per unit volume in an improperly distilled spirit compared to a home-brewed beer is higher or lower?
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You really don't have any idea what you're talking about here do you? You're just regurgitating some crap you probably read off of ask.com or yahoo answers without any grasp of reality and it's obvious.
If you want to discuss facts, let's appeal to a higher authroity on the matter... I'll take it a study from the EPA will suffice?.... great..
Let's review this study and then we can begin our little pissing match from there... Naturally, I'm going to highlight bits and pieces that support my point of view and you're free to do the same... After-which we will let the court of public opinion decide...
OBJECTIVES: In the past, some moonshine products contained potentially toxic contaminants. Although moonshine production continues in the United States, no studies have analyzed the content of moonshine since the early 1960s. We hypothesize that moonshine continues to contain potentially toxic concentrations of contaminants.
METHODS: Forty-eight samples of illicitly distilled moonshine were obtained from law enforcement agencies. An independent laboratory, blinded to both the moonshine source and a control sample of ethanol, conducted the analysis. Lead content was determined using atomic absorption spectrophotometry with a graphite tube atomizer. Alcohol content, including ethanol, acetone, isopropanol, methanol, and ethylene glycol, was determined using gas liquid chromatography with flame ionization detection.
RESULTS: Ethanol content ranged from 10.5% to 66.0% with a mean value of 41.2%. Lead was found in measurable quantities in 43 of 48 samples with values ranging from 5 to 599 parts per billion (ppb) with a mean value of 80.7 ppb. A total of 29 of 48 (60%) of samples contained lead concentrations above or equal to the EPA water guideline of 15 ppb. Methanol was found in only one sample at a concentration of 0.11%. No samples contained detectable concentrations of acetone, isopropanol, or ethylene glycol.
CONCLUSIONS: Many moonshine samples contain detectable concentrations of lead. Extrapolations based on the described moonshine lead content suggest that chronic consumers of moonshine may develop elevated lead concentrations. Physicians should consider lead toxicity in the differential diagnosis when evaluating patients consuming moonshine.
http://hero.epa.gov/index.cfm?action=reference.details&reference_id=1047133
So you see... it's not the Methanol you need to be so concerned with.. it's Lead... (We'll address both matters individually.)
SPEAKING OF LEAD.:
43 of 48 of sampels in the study had lead.. One is only left to ASS-U-ME that the other 5 did not... Why is that? If it were a problem with the mash itself you might wonder then why was lead not found in ALL samples.. The answer is obvious - it's the equipment used to distill.
Take into consideration that there are no standards or regulatory bodies on the construciton of back yard stills. People are free to use what they wish.. Quite commonly, stills are made up of a good amount of copper. How does one mate copper?. Probably the most common and traditional way is to use solder and sweat fittings. What is solder made up of? Just your run of the mill drive down to radio shack and get it variety is largely tin and lead.
If you weren't a plumber, had no knowledge of building codes, failed to do any reasearch first and just jumped right in you would likely assume solder is solder.... FALSE.. There is leaded solder and then there is the lead free variety specifically used for plumbing. But even "lead free" solder can contain up to 0.2% lead. Even today's copper alloy fittings which are commonly used to connect copper pipes an commonly found in a still build can still contain lead.
http://www.copper.org/environment/sdwa/sdwa_faq.html
Alcohol is a solvent and when vaporized under pressure in a still is going to pick up whatever impurities are introduced to it - lead from shoddy constructed stills using leaded solder for pipe fittings included...
Another practice some 'shiners' put to use is using an old car radiator as a condenser. Guess what. They contain lead! There is yet another source! I even saw one condenser design where someone was stripping out the heating elements of old baseboard heaters because of the fins in order to make an air-cooled condenser. I'd give him an 'A' for creativity, but an 'F' for common sense.
The point of the fact is simple: Exercise a little common damn sense. If you don't want impurities in your alcohol - don't introduce them in the first place. Stick to stainless steel and pure copper. Use only new copper certified for drinking water and only use something organic and non-toxic (see flour paste) to seal it all up with.
METHANOL (wood alcohol):
Only 1 sample...out of 48 had it.. only one. Why? I have no idea.. Maybe the shiner didn't pull off the heads. Could have even been the mash he used, but by and large it apparently isn't the widespread problem it's made out to be.
Here again a little bit of research and common sense applies.
FACT: When fermenting part of the process will produce a slight amount of methanol.
FACT: It takes pectin for yeast to work on to produce methanol.
FACT: Pectin counts are found much higher in fruits than in grains (Apples and Peaches containing some of the highest counts.)
Here is a nice little aricle about Aspartame dangers but at the same time does a nice job of explaining the relationship between Methyl Alcohol and pectin.
http://articles.mercola.com/sites/articles/archive/2012/11/11/aspartame-dangers.aspx
FACT: Fermenting a straight sugar/water wash produces zero Methanol (zero pectin - zero Methanol).
FACT: Methanol boils off at a lower temperature (at around 148 deg F @ 14.7PSI or 1 BAR.) than Ethanol (closer to 178 degrees) so contrary to your position.. with a controlled heat source yes you can separate them and depending on the technique you can separate them very distinctly like with a column reflux still. It's nothing that Joe in his back yard couldn't wrap his head around with a little research because Joe isn't necessarily a toothless hillbilly that counts to 20 on fingers and toes. "Joe" in many cases could be a Doctor or an Engineer, he might even be a Chemestry teacher so cast you stereotypes aside and forget what you've seen on the Discovery Channel.
But an any case, this is just another example of risk mitigation using common sense. Simply put, don't ferment apple juice, etc. Stick to grains and sugar. AND.. pay attention to what you're distilling.. Toss the stuff that comes off before 178 degrees. Or a good rule of thumb is toss the first 10ml for every gallon of wash you plan to distill.
I'M NOT DONE YET...
Getting back to the study.. now let's use their numbers and play that game... In the ONE sample that they did find Methanol. It was at a concentration of 0.11% or .0011 if you will
According to a Toxicity report from the EPA:
1. Humans - Ingestion of 80 to 150 mL of methanol is usually fatal to humans (HSDB 1994)
and
Density d20/4, 0.7915 g/mL Budavari et al. 1989
http://www.epa.gov/chemfact/s_methan.txt
This next reference from Wikipedia:
Methanol has a high toxicity in humans. If as little as 10 mL of pure methanol is ingested, for example, it can break down into formic acid, which can cause permanent blindness by destruction of the optic nerve, and 30 mL is potentially fatal,[17] although the median lethal dose is typically 100 mL (4 fl oz) (i.e. 1–2 mL/kg body weight of pure methanol[18]). Reference dose for methanol is 0,5 mg/kg/day.[19]
http://en.wikipedia.org/wiki/Methanol#cite_note-Vale-17
So now lets go off the absolute worst case example and lets use Wikipedia's info as the word of God in this instance. Given the stated concentration of 0.11% there exists the potential to consume roughly 1.1mL of Methanol if you were to drink an entire litre of the stuff.
That's a lot of alcohol and we're not talking about your off the shelf 40% ABV whiskey here. This stuff is very likely 60% at a minimum and potentially up to 95% ABV. My money is on you getting piss face drunk and passing out long before you got anywhere close to a dangerous concentration.
But let's say I'm wrong about that and you have God-like superpowers that allow you drink like a fish swims. You'd still need to consume almost 10 liters of the 'bad hooch' to get you to the 10mL mark!! That's over 2-1/2 Gallons Jack!! And oh, one more thing.. Those numbers assume you are drinking pure straight up Methanol but here comes the screw... The mass quantities of Ethanol you've been consuming all night is in and of itself an antidote to (drumroll please......) you guessed it. Methanol! Ethanol acutally inhibits your ability to metablolize the Methanol into formaldehyde and formic acid (what REALLY makes you go blind) since the enzyme alcohol dehydrogenase prefers the Ethanol.
In other words, IF there even is Methanol present... the Ethanol dilutes the Methanol - (figuratively speaking) so that you body can either A) metabolize it at a non-toxic level, or B) in an EXTREME case - and by extreme I'm saying you ingest 300mL plus... the Ethanol will hold off the metabolism of the Methanol long enough for you to get your ass to an ER and on some dialysis
You can read all about that tasty little tidbit here courtesy of the Western Journal of Medicine:
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC1306022/pdf/westjmed00175-0045.pdf
In Closing: The likelyhood of you injuring yourslef from distilling your own alcohol is already pretty low. If you apply a little bit of legwork to get the facts and add in a dose of common sense the the risk becomes remote in the extreme. It's like anything else.. learn how to swim before you dive in head first and you'll not drown. Swimming is a pretty safe and fun activity once you've learned how to do it. Same applys here.
OTOH, it's people like you that keep parroting the same old rubbish instead of searching for truth which is why this hobby is so widely misunderstood. Which ultimately leads to why we have stupid laws in place that have no basis and consequently people in jail having their lives stripped away over some nonsense. So next time before you go off half-cocked spewing a bunch of regurgitated blather and fearmongering and posting up funny faces to get your point across. Do us all a favor - do yourself a favor. Get the facts first.
K-Thx.