Full duplex IS considered "20/200", but it's a bit misleading. As has already been said, you can still only recieve at 10mbps, but you can send at 10mbps at the same exact time...simple math shows that 10+10=20, and that's where they get that number.

I'm sure it does help performance if your computer doesn't have to wait before it can send data back, and it can send confirmations immediately and such...
If you have a two computer network: forget about a hub or switch and buy/make a crossover cable. If the NICs are communicating directly they can support 100BaseTX at full duplex.
If you have more than two computers on your network, your best bet is to get a switch. Hubs don't support full duplex, unfortunately.