hi,
it is different if you have installed the nvidia sw ide controller. this makes the ide devices look liks scsi ones in the control panel. i was not able to figure out how to tell it dma was enabled but a performance check showed that it must be. unfortunately i kept getting "disk error during paging" errors with the nvidia driver and had to fall back to the standard xp drivers. just check performance of your drives, if you are in pio mode, it'll be obvious.
good luck