I see no reason why your CPU should not post at 133fsb, given a proper default multiplier.
Hopefully someone can shed some light on this for us.
My Duron 700 has no problem at 133 but in this case the factory default multiplier is 7 and with a 133fsb is only 998mhz, not much of a problem for these CPU's, given that you have a good HSF. If it had been a 750 or higher, I would probably have had to set a lower default multiplier with the CPU bridges, per the artical that I listed earlier.
If you truly want to get to the bottom of the issue you may want to do as the article states and try setting the bridges at a safe default multiplier for the 133fsb (one that you know you want to run at, as well as one that you know will post).
On the other hand, if you are happy with it at 100fsb, you may not want to bother.
Good luck, and if you decide to hardwire a new default multiplier with the bridges, let us know how it goes.