Forget about RAID 0 - it cuts your reliability in half, you need to use identical drives and it WON'T solve your I/O problem, it will just reduce it. RAID 0 is simply the striping of two (identical) drives for (theoretically) double the read and write performance; the two drives behave like a single, faster drive. If either drive fails in Raid 0, you lose all your data.
If you want to do RAID 0, you can't half-ass it. You need to back up your data, and I would strongly recommend first time RAID 0 users of having a third hard drive for backup of the RAID 0 array, at least until you get it configured (if you get a second drive and try to put your drives into RAID 0, you will either lose all of your data or have to do it in Windows, which is unreliable and can take days).
You should do what Duvie said: Keep Windows on one OS and buy a second hard drive to be your data/storage hard drive. Burn CD's off that second hard drive, etc while CS:S or any game/program runs off the first hard drive.
The reason you're getting slowdowns is because games need to stream data off the HD, but burning/encoding/etc also needs to stream data off a different part of the drive. The drive heads have to jump all over the disc while doing these two things at once and this causes slowdowns -- the HDD becomes the system bottleneck. To solve this problem, get a second large HDD to be your storage disk, and do all of your burning/file storage on that drive.
If you want the fastest performance, get a Raptor for your primary drive; however this route is more expensive (and the 1st generation Raptor is a bit noisy/whiny due to not using fluid bearings, and not that fast these days - barely faster than current generation SATA2 drives), you may as well keep your current HD and just add a second drive for storage. That's the easiest and cheapest route.
I ran a WD Raptor 36GB for 6 months and then the faster/quieter 74GB Raptor for a year as my boot drive; Raptors do give you faster boot times and game loads (especially the 74GB model), but the improvement is in the range of 10-15%; if storage space is tight, I'd recommend just getting a large drive for your main HDD (like a 250GB SATA2 drive with 16MB of cache, eg. the Seagate 7200.9) and partitioning it - the drive isn't that much slower, and you will get a lot more storage than on a Raptor.