All the memory modules in the dual-channel kits are "normal" 64-bit DDR SDRAM (well, unless they're R-ECC, in which case they're 72-bit 😱).
Look at the various Crucial PC2100 modules and let's take the 256MB PC2100 module as an example. They make three versions. One has four chips on it, another has 8 chips on it, and the third has 16 chips on it. You could get your motherboard to run dual-channel mode using two of the 4-chip ones, or two of the 8-chip ones, or two of the 16-chip ones. However, you could not do it with a mixture of them, because now the logical organizations of the modules don't match and so the motherboard cannot make a 128-bit wide "super-module" out of them anymore.
So the risk you run is that you'll buy a module, and then go to buy a second one and it is not the same. For this reason, you would want to buy a dual-channel kit so the modules are guaranteed identical.