The CPU runs at a 100Mhz DDR (200Mhz effective) bus.
You have your choice of running the RAM at 100 or 133Mhz, you get to pick.
Most people will choose 133 becuase it's a bit faster, but if you already have PC100 you can certainly use it.
And hell yeah try running it at 133Mhz, then pull it back to 100 if it's unstable.
My orignal sdram (66mhz spec) ran just fine at 100Mhz, and I know lots of PC100 RAM that runs happily at 133.
Do it, you can't hurt anything, if you have stability issues, just set it back to 100Mhz.