No, this is impossible. The mainboard chipset merely provides the bus bridge from PCI to IDE. The IDE drives itself follow the same arrangement we had back in 1983 in the first IBM AT - one controller steering two drives. Only that the controller isn't an ISA card anymore, and has been pulled into the (Master) drive. The IDE cable is ISA on steroids, but in the programming model, no change ever. There is only one active controller on a given IDE channel - in the Master drive. It controls both its own and the Slave's storage media, and can only handle one request at a time.
The outcome is, if you use one of the drives at 100 percent, then the other drive will be unusable, no matter how fast the interface is in comparison to the drive's actual throughput.
regards, Peter