It all depends on the job field and exactly what is on the resume.
For example, if you're a bit older and you have basic office skills and a nice work history, it wouldn't make much sense to put education first because it may have been a decade or more since you've been in school. If all you have are the basic required skills then it doesn't make much sense to put that first because a first impression from a potential employer is that you are a dime a dozen.
In this situation it sounds like education should come first and foremost. If you are a student, then it should go without saying that you've been spending your time focusing on your studies instead of focusing on trying to mantain a non-professional job while in school. If your work experience is very limited, then you probably want to put that last... so it would be Education >> Skills >> Work Experience.
PM me a copy of it and I will help.