Originally posted by: sgtroyer
The reason none of these methods produce white light has to do with the nature of white light, and the physics of light production from ionized gases. White light is a mixture of different colors. There is no such thing as monochromatic (one color) white light. A neon tube, or fluorescent, works by exciting the electrons in a gas. When the electrons drop back down, they emit a photon. The wavelength of the photon (color) is precisiely determined by the energy difference between he excited and resting electron energy levels. Since all of the photons produced by a particular gas have the same wavelength, you get monochromatic light: one color. There's no way to get the mixture that produces white light. Using the phosphor coating on the tube lets monochromatic light produce white light.
Note: LEDs have the same problem, you can't produce a white LED because they are inherently monochromatic. White light from LEDs requires either three LEDS (red blue and green), or an LED with a phosphor coating.