Welcome to the club vevo

I'd say anything tech wise is good for the base layer. Helps wick sweat away and prevents the awful cotton chafe on your nipples...or worse.
For layers over/above that - a cotton shirt/hoodie is fine over that. It's really just keeping your core warm. People will argue "then your sweat soaks into the outer cotton" - true. If you have the money to buy technical long sleeve stuff go for it. (Brand for the most really doesn't matter - even Target stuff is pretty good)
I will say - you'll figure out quickly what works for you, what doesn't. I kind of have a rule based on weather/wind:
55+ - no shirt
47-55 - short sleeve shirt
35-46 - long sleeve over short sleeve, thin gloves
under 35 - hoodie + long/short sleeve, thick gloves
All varies based on wind of course. What works for me doesn't work for everyone...just experiment and you'll figure it out.