Capacitance and voltage are both constants. It will only change when you start connecting multiple capacitors in parallel or series configuration.
Parallel connection is simply additive.
Series connection is much more complex and I don't know much about it.
When you connect two 200V 500µF capacitors in series, it will become 400V 250µF. Even though it doesn't look like it, it make sense, because the energy is in linear function of capacitance and square of voltage, thus 1/2 x 4=2 You have two capacitors of same energy storage and energy is effectively doubled.
J(joules)=1/2 c x v^2
C is in farad, not µF
0.5 x 5^-4 x 200^2=10joules
0.5 x 2.5^-4x 400^2=20joules