C6H5NO2 can be reacted over Fe, dilute HCl, and heat to form Anilinium chloride, C6H5NH3+CL-, and then with Na2C03 to form C6H5NH2.
Hydrogenation of a nitro compund to an amine takes place smoothly when a solution of the nitro compound in alcohol is shaken with finely divided nickel or platinum under hydrogen gas.
Examples: C6H5NO2 --(H2, Pt)--> C6H5NH2
Chemical reduction in the laboratory is most often carried out by adding hydrochloric acid to a mixture of the nitro compound and a metal, usually granulated tin or iron. In the acidic solution, the amine is obtained as its salt,; the free amine is liberated by the addition of base, and is steam-distilled from the reaction mixture.
C6H5NO2--(Sn, HCl, heat)--> (C6H5NH3+)2 SNCl6 2- --(OH-)--> C6H5NH2 + SnO3 2- .