Do be careful with a PC PSU. There are large capacitors which are charged to high voltages. Typically 360-370 V (That is not a typo). In the case of Active PFC PSUs, the main capacitors are charged to even higher voltages (380-400 V).
These voltages at least as dangerous, and probably more, than main electricity.
However, the total energy stored in the capacitors is small - and will dissipate rapidly when the mains supply to the PSU is interrupted. If there is a standby power LED on the mobo, this may remain illuminated for 5 or 10 seconds after the PSU is unplugged from the mains. Then the LED dims, often accompanied by a chirp from the PSU as the electronics try desperately to keep the output voltages up, as the capacitor voltage plummets towards zero.
If you leave the PSU unplugged from the mains, but plugged into a load (like a mobo) then the charge should dissipate to safe levels within a few seconds, and dissipate completely within an hour. If you want to be sure, then you can discharge the caps with the techniques listed above (ideally using a resistor).
NOTE THAT THE ABOVE DOES NOT APPLY IF THE PSU IS FAULTY. A Faulty PSU may be able to charge the caps, but not discharge them - a lethal charge could remain for minutes, hours or days (depending on the fault). DO NOT OPEN A FAULTY PSU UNLESS YOU ARE COMPETENT TO HANDLE AND ASSESS THE SAFETY OF, AND DISCHARGE HIGH VOLTAGE CIRCUITS.
You are very unlikely to get a shock from a working PSU that has been disconnected from the mains for more than about an hour - though of course, some care is needed. In particular, care when reassembling is essential to avoid any stray metal, or screws that may contact high voltage components, and to make sure that a good seal is made to prevent debris or fingers from getting in.
Anyway, some other points:
Take a 1000microF capacitor, charge it (~24V) and then discharge it on your self
See how FUNNY it is
What is this supposed to prove? Such a capacitor charged to 24V is completely harmless. Indeed if you pick one up by the terminals you probably won't even feel it (unless you pick it up with your tongue - in which case it will give you quite a bite, but won't do you any harm). I have worked with 30 V circuits, sometimes with bigger capacitors - I certainly don't recall even getting a tingle from the supply (or caps). Voltages below 48V are classified as Safe Extra Low Voltage (SELV) - essentially, SELV voltages are sufficiently low, that an injurious accident is exceptionally unlikely. The circumstances required for injury are difficult to achieve - generally needing electrodes penetrating the skin, or a large area of skin wrapped in metal foil.