Originally posted by: Zenmervolt
They are not the same thing.
4WD properly involves locking front and rear differentials and a transfer case that has a low range option.
AWD can use several methods, but it does not lock all wheels together the way that true 4WD does and will not offer the same level of traction in severe situations. However it requires less driver intervention and is overall "better" in 90% of all on-road situations because of not requiring driver action.
ZV
When you engage the 4wd on a normal transfer-case based all wheel drive system, you don't lock the diffs. the rear and front diff are open (maybe limited slip or air lockers if the vehicles is a serious off roader), but there is no differential between them - the front diff and rear diff will spin at the same speed. For this reason it is damaging to the vehicle to drive it in non-slippery conditions with 4WD engaged, in a turn the front wheels cover more ground, but if they are locked to the rear wheels, the tires must slip a small amount to make this happen, and it's extra wear on the system.
In an AWD car you have a diff in the middle connecting the front and rear diffs, so you don't have any problems driving on the road. Most AWD cars don't give you the option to switch it off. This means that it is possible for all the power to be spun out on just one wheel, with 4WD you'll have at worst two wheels spinning, with locking diffs you get all four.
Assuming open diffs, AWD will be more likely to get stuck.
Of course, most AWD vehicles on the market have some clever limited slip stuff going on in the diffs, and that changes things.