OP, what direction is that side of the house on? If you're in a west facing room, you're fighting that afternoon/evening sun, and that would be one big reason why your room is getting so hot.
A number of things to try: reflective window film (you can probably buy it at any hardware store, Lowes and Home Depot carry it for sure); blinds/shades and curtains on the window (the more insulating air you can trap by the window, the less heat is radiating in through there); ceiling fan or small desk fan (I have one in my bedroom/office space, and it does an amazing job of cooling me off while I'm in there); window a/c.
Those are pretty much in the order of what I would try, if I were you. If you can score some mirror tint, that will work even better than the reflective tint sold at hardware stores. When I had my first apartment in Guam, the living room window faced west, and made it blazing hot in the afternoons. I asked for and received permission to tint the window, and picked up some mirror tint from my local Ace hardware. Knocked the temp in the front room down a good 10-15 degrees! :thumbsup: