BFG10K, I dunno about that. I thought that I had read on another site that someone had asked an ATI rep about the (apparently) extremely-high temps of their card, and the ATI rep had stated that they are good for (some number above 100C), without damaging the chip.
Also, there was another thread about exactly this, on either the GH or Video forums, posted by someone that had flashed their X800 Pro to an X800 XT, and noticed the insane temps (since the ATI "overdrive" tool is enabled with the X800 XT BIOS flash, and the temps were now visible). All of the replies that I read in that thread, indicated that temps near 80C under load were in fact normal.
Another thing, about the huge disparity of temps between idle and under full 3D load - the drivers actually change the voltage when running in 3D mode, that increases the power-dissipation/heat quite substantially too. So that huge change in temp isn't solely due to load, but also due to more power being pushed into the chip.
As long as the card is stable, I wouldn't worry, although I might tend to wonder about the overall longevity of the card at those temps. Makes you wonder a bit about possible electromigration effects too, if those are "real", since they supposedly occur more often at higher temps.