My work blocks all web mail sites and all the normal ISP ones (Comcast, Verizon, etc). Whats funny is that gmail.com is blocked, but mail.google.com is not. Try that.
It's up to your IT department as to what they allow and what they don't. I used to have to Remote Desktop to my home PC via port 23 and get to gmail from there when I needed it. Current job has it open though.
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