Hey bud,
Some really colorful metaphors given, probably the most important take away unless you're held accountable for such measurements...
That said, and without beating it with derivations and some *basic/repulsive* (who you're asking) physics - here's a straight forwardish attempt at clarifying a relationship common people rarely can tell apart, or remotely care in all fairness.
So, the one with maybe the least ambiguity given the question, Voltage. As said, analogized, this metric is about the difference in electrical potential between two points (crucial) so that a current of one ampere traversing the plane ("imaginary force field" in between those points) expends 1 Watt(*will return to*) of power in the process = 1 Volt. Alternatively, a Volt can be defined as one joule/coulomb, as well as other equal definitions probably not beneficial in clarifying. Also, the units i used will come full circle in a second...
Now, a watt. Defined as a particle(object) held at a constant velocity of 1-meter/1-sec opposed by a force equal to one newton, resulting in the rate of work done = 1 watt. So, 1-watt=(1-Newton*1-Meter)/1-second <=> 1-watt=1-joule/1-second. Think of this as how "expensive" in terms of how much work an element, or object is to operate, as well as a way of setting a maximum before an object is "overworked" (or minimum). In circuits, or considering watt unit electrical measurements, if a lightbulb is given as a 50-watt rating - then when in a closed circuit it will be absorbing (taking work) from the source at 50-watt, where as the source will be (lets say its a one bulb circuit) providing (--50 watts) (perfect world).....where the sign identifies an element as receiving or supplying (+ receiving, -- supplying).
I've tried using as few of units not to belittle anyone, but just to bring the seemingly "evasive" definitions into the whole later on hoping to best clarify the difference between them. The remaining measurement, Ampere is a factor in electrical circuits concerning watts - as watts don't act alone in the whole picture, but more as a "demand." Leading us to the definition of 1-Ampere being approx. equal to getting a "bunch of electron charges" to pass a point in a circuit PER 1-second. More accurately, 1-Ampere=6.214x10^(18) electron charge carriers (electrons)/1-second. <=> 1-Ampere=1-Coulomb/1-second. This "bunch" or stupid-big number (if one electron were 1 penny, a coulomb would be $62.4 QUADRILLION dollars!!! yikes) might help answer your second question, how accurate are these.....
Well, I think you could imagine we're dealing with a huge quantity of ridiculously small electrons, each weighing ~9.1x10^-31 kilograms (which means nothing to me too - so if the "size" of that number, |9.1x10^31| were inches - it would be more than 2000x the diameter of what we consider the universe!!!!)
So to conclude with the hazards, and although we're "departing" my area as I'm no doctor, or really all too familiar with biology etc., I'll try sticking to the electricity involved. First, whether we're using AC or DC plays a huge role, point of contact, general cardio health, or even how sweaty a person happens to be, are also significant variables in the shock & death - using a rough values(DC) we can say as little as 500mA (dont let 500 fool you

...) or 0.5A can cause fibrillation and death. Now, disredgard any folklore like "the voltage doesn't get ya, its the amps!" yada yada....Remember, V=Amps * Resistance or more simply - they are both in the mix! SO think of it in terms of Watts which is P=v^2/r <=> P=Volt * Amp so if we only had 1/2 an Amp at 120V we'd be looking at a power rating in one second of 60 W - with 110W being a rough daily expended by an adult male. Also the same as 60V @ 2 Amps, or 30V @4 amps or a little more than the shock received from 200V with human resistance of ~ 2100Ohms....with people being "resurrected" using about 5V/cm (defib)....
I hope I clarified a pretty roundabout relationship....it's a lot of different quantities and actions that form as an equality (why it''s better to think, "It's the Electrons that'll kill ya") and i'd avoid thinking of it like the simile because if you're on Anandtech I know you're more than smart enough to think of them independently - hopefully passing that wisdom forward
Best of luck, never stop asking why....
AxilleasT
*death or shock data googled with loose values used more to illustrate than talk electroshock peculiars....Slap me with corrections if you like*