There are several variants of the A7V333, which one do you have? A7V333, A7V333-RAID, A7V333-X or another of the -X family? The "333" comes from the KT333 chipset used on these boards, which supports the DDR333 memory. You can find more info about what CPUs are supported using Asus'
CPU Support Tool.
Original-type A7V333's (meaning the A7V333 and A7V333-RAID) do support 333MHz-based Thoroughbred and Barton CPUs if the BIOS is updated to 1016
and if the PCB revision is 2.0 or higher (mine is a 1.02, you can find the revision number printed below the "A7V333" logo on the board).
If you have one of the -X models, PCB 2.01 or later will likewise support 333MHz-based Thoroughbreds and Bartons, too.
Hope that helps!

Welcome to the Forums, and if you do have one of the original A7V333's or A7V333-RAID's, you can find quite a bit of end-user info
here. There is one update to the info I posted there: Motherboard Monitor can now get you readings directly from the CPU's onboard thermal sensor.