Can someone take a look at my post above and perhaps give some feedback? Would be great Thanks!
First of all, WoW doesn't scale properly with crossfire and sli.
Your video card upgrade shouldn't decrease FPS like that. I had that problem very long ago when switching vendor and the driver was not uninstalled properly, which the performance dropped significantly.
Here is what you should do first before buying anything if you haven't reinstall your OS after switching card.
Download and install ccleaner.
Boot in safe mode and uninstall
any video card drivers.
Reboot back in safe mode, manually delete any folders containing those drivers. Reboot again in safe mode and run ccleaner on the registry. It will remove any reference to non-existence files.
Reboot in normal and download and install the latest CCC 10.4.
Rerun ccleaner again on registry. You may want to clean up your HDD a bit with ccleaner too, just remember not to remove cookies or you will lose all stored passwords.
Defrag your HDD. Reboot and start WoW with all mods disabled. You can enable all mods afterwards.
If the above doesn't help, simply disable one of the card and try again.
So that you know, I have setup a PC with GTS 8800 640mb running WoW for a friend at max setting without any visual issue. Having 20 ish FPS is one thing, seeing shuttering effect is another. The game should still be very playable running consistently at 20-30 FPS unless it runs it runs at 60+ 50% of the time but 0 for the other half. I believe what you are experiencing is
"shuttering effect", which has nothing to do with the video card setting. It happens when there is a driver/resource conflict. It will also happen when your system has a bottleneck, but in your case there shouldn't be one unless you are in 25 man raid, and of course Dalaran.
Crossfire or sli setup requires very fast memory as well as very fast HDD and a NIC with onboard NPU to play well on MMOs.