What res?
I would think that dual core could bottleneck in some games. Have you tried unlocking it?
your dual core is going to be the bottleneck on the major multithreaded titles before the 6950 is.
if you play BC2 and plan on playing BF3(for example), upgrading to a phenon x4 would be the first step
no way would I crossfire 6850 on a dual core cpu. not only would it hold back that much graphics power in general in some games but the additional cpu overhead would limit performance even more. of course your res is important here to as already mentioned. and I have never heard of that psu and question whether it is a quality unit capable of handling the upgrade anyway.
EDIT: I see you posted your res now and I still say no to crossfire with your dual core cpu.
1920x1080. I have tried, it wont boot into Windows 7 x64.
I have a 6850 not 6950. Don't know if that was a typo or if you based your conclusion on the wrong GPU.
that psu would be pushing it a bit for 6850 crossfire with your current system and really pushing it with an oced quad core.