If you overclock that Athlon 64, you will get a considerable boost in performance, in scenarios were the game is not optimized for dual core, the difference between single core and dual core based on the same architecture is non existent, will tend to be more GPU dependent. If you are able to upgrade that CPU to a Dual Core would be nice though, Pentium 4 is the worst CPU for gaming, that's why I ditch my P4 EE 3.4GHz for the current CPU I own which in many scenarios were the game is not Dual Core Optimized, it can be as fast as an Athlon 64 X2 4800, and sometimes even faster. So if you can't upgrade your CPU, overclock it, or do an upgrade if you got the budget. That CPU will bottleneck the card, but not in the level that Pentium 4's do.