Also, not many people want to actually machine silver. Since no company would make it, a true enthusiast would make it themselves.
Currently, I am making my own aluminum heatsinks to cool 2 harddrives. Ill show pictures when its done in 2 weeks. The machinest who is doing this for me gave me discount on the work so its free. But basically, 12" x 3/4" x 6" aluminum slab costs about 120$. Each fin takes 30 minutes to make, and there are 18 fins per heatsink (2 heatsinks). Machinests normally charge 60$ per hour of labor.
Do the math, the total charge would be $1080 for the heatsink labor, 120$ for the material, for a total of 1200$. That is wicked expensive for just 2 alumium slab heatsinks, but its a ton of careful slow work. When milling a heatsink out of a solid slab of aluminum, going below 1/8" thickness on the contact surface, and 1/16" thickness of fin can result in the whole thing collapsing on itself whether that is under the pressure of the vice, or the resonation of the piece upon milling.
So, moral of the story, if silver is 7$/ 31.1 grams, and you start with a 4"x4"x4" silver block, i would wager that would weight something like 3kg and the cost to be $675.
Labor would be around 22 hrs especially if the fins are thin, so thats an additional $1320.
If you machine something for 22 hrs you probably want to spend 40 hrs designing it (based on measure twice, cut once).
so, 2000$ for a silver heatsink that has oxidized and lost its thermal conductivity advantage over copper. In addition, good silver may be too soft and bend too easily.
So, Ag is not cost productive for any application.