Radioactivity is a property of individual isotopes of each element. And it results from the breakdown of the arrangement of particles in the NUCLEUS of the isotope, having nothing to do with the electrons surrounding that nucleus. An isotope is considered unstable if it does spontaneously break up part of that nuclear structure and emit a particle or energy wave.
An ELEMENT is defined specifically by the number of PROTONS in the nucleus. This is its ATOMIC NUMBER. The nucleus also contains a some NEUTRONS. The NUMBER of neutrons in a nucleus of the same Atomic Number is how the different ISOTOPES are defined. In general, having more Neutrons than Protons is less stable, and the greater the excess the less stable. A larger excess of neutrons is likely to mean a much less stable isotope that WILL break apart quickly and cease to exist. So for the LIGHT ELEMENTS and the probability of having several different isotopes with increasing neutron count that are stable enough to exist is much smaller than for heavy elements. Among the heavier ones, there are many with FEWER Neutrons than Protons, and that opportunity is very limited for the light elements with few protons to begin.
For each element there are found to be in nature a particular distribution of isotopes. LOTS of the most stable isotope, and small amounts of the less stable ones. In fact, that distribution is slightly different depending on where that sample its taken, which reflects how long that sample has existed since it was made and left there. What the Periodic Table shows as the ATOMIC MASS of each element is the AVERAGE mass of samples we have examined, taking into account the actual mass or each isotope and its relative abundance. So the values are never whole numbers, but always decimal fraction numbers.